The sea surface microlayer covers the upper 10 to 1000 micrometre deep boundary layer of the ocean where important physical, chemical, and biological processes take place. As turbulence is damped close to the surface molecular transport processes take over the transfer of momentum, heat and mass from the upper ocean to the sea surface. As characterictic features molecular sublayers estend from the surface to depths of about 1000 µm (viscous sublayer), 500 µm (conductive or thermal sublayer), and 50 µm (diffusive sublayer). The conductive sublayer is also referred to as the cool skin. The structures of the molecular sublayers are complex due to the variability of wind stress acting on the sea surface, due to heat, radiative and gas fluxes crossing these layers, and due to rainfall. A schematic vertical section through the ocean is shown in Figure 1. The logarithmic scale ranging from the diameter of a molecule to the maximum depth of the world ocean underlines the importance of the top millimetre of the sea.
Among the main concerns in the temperature difference across the cool skin of the ocean has been the interpretation of satellite-derived sea surface temperatures as equivalent to in-situ bulk temperature measurements under clear-sky conditions, the only case where space-borne infrared imagery can be used to monitor the sea surface. While common in-situ measurements of sea surface temperature are representative for the upper decimetres or metres of the bulk water infrared radiometers receive radiation from the upper few micrometres only. Besides this trouble of the remote sensing community growing interest in the cool skin of the ocean is expressed by the possibility to parameterize the air-sea gas-transfer coefficient. While field measurements of the gas transfer have been often inconclusive the similarity of the transfer of passive properties such as gas and heat allows the extrapolation from the molecular thermal conductivity to molecular diffusivity. The latter interest is not restricted to clear-sky situations but is of interest in cloudy and precipitating situations, too. The same is true for the impact of the conductive layer on the solubility of gases. Due to the temperature dependence of the solubility any gas transfer calculated with bulk temperatures will possibly be biased to lower transfer rates. Typical temperature differences across the conductive sublayer are of the order 0.3 K. However, the actual value varies with heat, radiative, and momentum fluxes in the upper ocean and is also modified by rainfall so that a range of variability can be expected from -1 K to 1 K.
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